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Barcelona edged Libertad 1-0 in the first leg of their Copa Sudamericana second-stage clash on Thursday.
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Ismael Blanco's 15th-minute goal was all the Ecuadorians needed to claim a key win at their Estadio Monumental Isidro Romero Carbo.
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Libertad will still fancy their chances of progressing when they host the return leg in Paraguay on Wednesday.
The game's only goal came on the back of a fine team move.
Matias Oyola was eventually freed down the left before he squared a pass for Blanco to power high into the net in a one-on-one.
It leaves Barcelona well-placed to reach the round of 16, but they will need a positive result away from home.
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