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Arsenal, PSG, Atletico, Bayern into last 16
Barcelona's Lionel Messi (L) and Neymar (2L) react as Manchester City's Jesus Navas (2R) and Ilkay Gundogan leave the pitch in Manchester, north west England on November 1, 2016
Meanwhile, Arsenal and Paris Saint-Germain both clinched qualification from the knockout stage from Group A.
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Last season's runners-up Atletico Madrid were one of four teams to clinch a place in the last 16 of the Champions League with two group matches to spare on Tuesday.
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Atletico beat Russian side Rostov 2-1 in Spain with Antoine Griezmann scoring both goals as they sealed their progress from Group D along with five-time European champions Bayern Munich, who were 2-1 winners at PSV Eindhoven.
Meanwhile, Arsenal and Paris Saint-Germain both clinched qualification from the knockout stage from Group A.
Arsenal came from two goals down to win 3-2 away to Ludogorets in Bulgaria to go through along with PSG, who were 2-1 winners over Basel in Switzerland.
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