Kane scored both goals as Tottenham came from behind to beat PSV Eindhoven 2-1 at Wembley Stadium on Tuesday, November 6.
The 25-year-old beat other nominees Riyad Mahrez who scored one goal and provided two assists as they beat Shakhtar Donetsk 6-0 at the Etihad Stadium.
other nominees for the award include Karim Benzema who scored two goals as Real Madrid beat Viktoria Plzen and Milan Pavkov with the two goals as FK Crvena Zvezda beat Premier League.
Cristiano Ronaldo Goal of the Week award
Juventus star Cristiano Ronaldo emerged as the winner of the Goal of the Week for matchday four.
Ronaldo scored his first Champions League for Juventus although they eventually lost 2-1 to Manchester United at home.
His goal was voted the best ahead of Manchester City’s Raheem Sterling curler in their home win.
Pavkov's outside strike against Liverpool and Otávio's goal in Porto’s 4-1 win over Lokomotiv Moskva.
Ronaldo will hope to have another goalscoring encounter when Juventus face off with Valencia in their next encounter.
Takumi Minamino wins Europa League award
Takumi Minamino has emerged as the winner of the Europa League Player of the Week award of matchday four.
He dethrones Chelseawho won the award for the previous matchday.
He scored a hattrick as Red Bull Salzburg beat Rosenborg 5-2 away from home in their group fixture.