Bieber joined Neymar in some training drills and also played penalty with Rafinha.
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The singer is in Barcelona on his current European tour and will perform at the City’s Sant Jordi arena on Tuesday, November 22.
Ahead of his concert, the 22-year-old visited Barcelona training ground where he met the likes of Lionel Messi, Neymar and Luis Suarez in training.
In videos released by Barcelona on Snapchat, the ‘Sorry’ singer is seen taking part in some drills with Neymar and Rafinha.
He went between the post in a penalty shoot-out but could not stop Rafinha from scoring from the spot.
When it was his turn to take a penalty, the singer blasted one over the bar but scored the other with a fine strike.