The recent deal signed by the actress follows a previous one with an IT solutions company.
She is to represent the brand with one of its edible products, 'Slimming Coffee'.
Aigbe made the announcement via her Instagram page on Wednesday, October 26, 2016.
She wrote, "Signed Deal......Meet the Brand Ambassador of Shape you Slimming Coffee @shapeyouafrica . To God be the Glory!"
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This is following a recent deal with Edalaf Brothers Limited, an IT solutions company based in Lagos.
Dr Falade Abiodun, the CEO of the company shared the organization's happiness concerning its new ambassador.
He said, “Mercy Aigbe-Gentry is an award-winning professional actress and fashion icon in Nigeria today. She is at the peak of her career and doing very well despite being a mother and a happily married woman.
"Mercy has proven to be morally upright, she is scandal free and she can move the youth of this nation. With Mercy Aigbe-Gentry as our face, we believe we will have the undivided attention of the Nigerian Youth and we can actually make the difference by guiding them in the right path to discovering their individual talents and following their passion."
Aigbe recently embarked on a trip to London where she attended the launch of a new television, Rok on Sky TV.